Experiment
Title
Ni K edge XAS transmission and XAS fluorescence of Ni complexes (with cysteine-rich ligands) at 10K
DOI
10.26302/SSHADE/EXPERIMENT_JD_20171122_001
Data reference
Pécaut, Jacques; Domergue, Jérémy; Duboc, Carole; Delangle, Pascale (2017): Ni K edge XAS transmission and XAS fluorescence of Ni complexes (with cysteine-rich ligands) at 10K. SSHADE/FAME (OSUG Data Center). Dataset/Spectral Data. https://doi.org/10.26302/SSHADE/EXPERIMENT_JD_20171122_001
Publications
Type(s)
laboratory measurement
Description
Study of Ni complexes based on tripodal cysteine-rich ligands at different pH
Variable(s)
observation mode, sample composition
Number of spectra
7
Instrument
X-ray Absorption Spectroscopy measured in transmission mode
Sample holder
Oxford-ILL orange cryostat
Standard medium
unknown
Observation mode
spectrum
Spectral range type(s)
hard X
Valid spectral range(s)
Min - Max ($eV$) Sampling ($eV$) Resolution ($eV$) Position accuracy ($eV$) Absorption edge
#1 8100.0 - 9186.0 0.427 $Ni$ (K: 8.3328 $keV$)
Comments
The resolution in the above table is the resolution given by the monochromator. The energy was calibrated by measuring the absorption edge of a reference: Ni metallic foil (first maximum of the derivative set at 8333 eV).
Observation geometry
direct
Observation mode
fixed angles
Observation mode
averaged
Instrument
X-ray Absorption Spectroscopy measured in fluorescence mode
Sample holder
Oxford-ILL orange cryostat
Standard medium
unknown
Observation mode
spectrum
Spectral range type(s)
hard X
Valid spectral range(s)
Min - Max ($eV$) Sampling ($eV$) Resolution ($eV$) Position accuracy ($eV$) Absorption edge
#1 8100.0 - 9185.0 0.427 $Ni$ (K: 8.3328 $keV$)
Comments
The resolution in the above table is the resolution given by the monochromator. The energy was calibrated by measuring the absorption edge of a reference: Ni metallic foil (first maximum of the derivative set at 8333 eV).
Observation geometry
directional
Observation mode
fixed angles
Comments
Emitted x-rays are collected in a solid angle directed at 90 degrees from the incident beam.
Observation mode
averaged
Variable type(s)
  • observation mode
  • sample composition
Date begin - end
2017-11-22 - 2017-11-28

Versions

Release date
2019-11-15 07:39:10 UTC+0000
Version (Date)
#1 (2019-11-15 07:30:44 UTC+0000, Updated: 2019-11-15 07:39:10 UTC+0000)