- Type
- Raman scattering
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| 2ν2 (A1g) | A1g | bending sym. out-p (wagging) | (CO3)2- | (CO3)2- | no | full |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 1726.5 ± 1.5 | - | 17.9667 ± 1 | asymmetric | 0.023996 | w | 0.047 | w | 295.0 | 1 |
- Label
- 2ν2 (A1g)
- Symmetry
- A1g
- Category
- overtone vibration
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Contribution level
- full
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | no |
- Primary specie
- (CO3)2-
- Label (type)
- 2ν2 (bending sym. out-p (wagging)) Bond: (CO3)2-
- Comments
- O-C-O out-of-plane deformation
Vibration modes
- Texture
- single crystals and powders
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Laser wavelength
- 532.0 nm
- Sample orientation mode
- unoriented
- Method #1
- spectrum fit
- Fit function
- Voigt
- Overlap
- isolated
- Peak
- 1726.5 ± 1.5 cm-1 (fit peak)
- Evaluation
- validated
- Quality
- B
- FWHM
- 17.9667 ± 1 cm-1 (fwhm)
- Shape
- asymmetric
- Evaluation
- undefined
- Quality
- C
- Method
- peak intensity
- Relative intensity
- 0.023996 ± 0.002
- Strength
- weak (w)
- Evaluation
- undefined
- Quality
- C
- Method
- width x peak intensity
- Relative intensity
- 0.047 ± 0.01
- Strength
- weak (w)
- Evaluation
- undefined
- Quality
- D
- Publication
- SSHADE spectrum