Band
Title
1136.5 cm-1: ν1 of 32S16O in natural SO in Ar matrix
Type
absorption
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν1 stretching 32S16O SO 32S=16O no
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
1136.5 ± 0.3 - 1.8 ± 0.2 symmetric 1 vs vs 20.0
Label
ν1
Category
fundamental vibration

Evaluation

Level
fully assigned
Evaluation
validated
# Multiplicity type Degeneracy Other band
1 no

Vibration modes

Label (type)
ν1 (stretching)       Bond: 32S=16O

Temperature

Temperature
20.0 ± 10.0 K
Method #1
spectrum measurement
Overlap
isolated
Peak
1136.5 ± 0.3 cm-1 (peak)
Evaluation
validated
Quality
A
FWHM
1.8 ± 0.2 cm-1 (fwhm)
Shape
symmetric
Evaluation
undefined
Quality
A
Method
peak intensity
Relative intensity
1
Strength
very strong (vs)
Evaluation
undefined
Quality
A
Method
estimated
Strength
very strong (vs)
Evaluation
undefined