Band
Title
1302.8 cm-1: ν3 of 32S16O18O in natural SO2 - phase I
Band type
Type
absorption
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν3 unknown stretching asym. 32S16O18O SO2 =32S=18O no no
Characteristics summary
Peak position
(cm-1)		 Center position
(cm-1)		 Width
(cm-1)		 Shape Asymmetry factor Peak intensity
(cm-1)		 Peak intensity relative Peak strength Integrated intensity
(cm-2)		 Integrated intensity relative Integrated strength Temperature
(K)		 Pressure
(bar)
1301 ± 0.5 - - unknown vs 20.0
1302.8 ± 0.4 - - shoulder vs 90.0
Band assignment #1
Assignment
Label
ν3
Symmetry
unknown
Category
fundamental vibration

Evaluation

Level
fully assigned
Evaluation
validated
# Multiplicity type Degeneracy Other band
1 no no
Primary specie
32S16O18O

Vibration modes

Label (type)
ν3 (stretching asym.)       Bond: =32S=18O

Temperature

Temperature
20.0 ± 5.0 K
Method #1
spectrum measurement
Overlap
unknown
Peak
1301 ± 0.5 cm-1 (peak)
Evaluation
undefined
Quality
A
Shape
unknown
Evaluation
undefined
Method
estimated
Strength
very strong (vs)
Evaluation
undefined

Temperature

Temperature
90.0 ± 15.0 K
Method #1
spectrum measurement
Overlap
shoulder-tail
Peak
1302.8 ± 0.4 cm-1 (peak)
Evaluation
undefined
Quality
A
Shape
shoulder
Evaluation
undefined
Method
estimated
Strength
very strong (vs)
Evaluation
undefined
Publications
Data publication experiment