- Type
- absorption
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| O2- → Fe3+ or 6A1 → 4E, 4A1 | unknown | Fe3+ | unknown | full |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 22000 ± 500 | - | 8600 ± 500 | symmetric | 1 | unknown | 1 | 298.0 | 1 |
- Label
- O2- → Fe3+ or 6A1 → 4E, 4A1
- Category
- electronic transition
Evaluation
- Level
- uncertain assignment
- Evaluation
- undefined
- Contribution level
- full
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | unknown |
- Primary specie
- Fe3+
- Label (type)
- O2- → Fe3+ or 6A1 → 4E, 4A1 (unknown)
- Comments
- ligand-to-metal charge transfer (Marusak et al., 1980) or crystal field (Sherman and Waite, 1985)
Electronic modes
- Temperature
- 298.0 ± 1.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Method #1
- data compilation
- Overlap
- strongly blended
- Peak
- 22000 ± 500 cm-1 (peak)
- Evaluation
- validated
- Quality
- E
- FWHM
- 8600 ± 500 cm-1 (fit fwhm)
- Shape
- symmetric
- Evaluation
- validated
- Quality
- E
- Method
- peak intensity
- Relative intensity
- 1 ± 0.05
- Strength
- Evaluation
- undefined
- Quality
- C
- Method
- width x peak intensity
- Relative intensity
- 1 ± 0.05
- Evaluation
- validated
- Quality
- C