- Type
- absorption
- Assignments summary
- Characteristics summary
| Assignment | Symmetry | Mode | Specie(s) | Molecule/Atom | Bond | Multiplicity | Degeneracy | Contribution | Resonance |
|---|---|---|---|---|---|---|---|---|---|
| 3ν3 | stretching asym. | (CO3)2- | (CO3)2- | accidental degeneracy | accidental double | unknown | |||
| 2ν3+2ν4 | combination vibration | (CO3)2- |
(CO3)2- (CO3)2- |
accidental degeneracy | accidental double | unknown |
| Peak position (cm-1) |
Center position (cm-1) |
Width (cm-1) |
Shape | Asymmetry factor | Peak intensity (cm-1) |
Peak intensity relative | Peak strength | Integrated intensity (cm-2) |
Integrated intensity relative | Integrated strength | Temperature (K) |
Pressure (bar) |
|---|---|---|---|---|---|---|---|---|---|---|---|---|
| 4275 ± 5 | - | 68 ± 2 | asymmetric | 3.0e-04 | w | 295.0 | 1 |
- Label
- 3ν3
- Category
- overtone vibration
Evaluation
- Level
- fully assigned
- Evaluation
- validated
- Contribution level
- unknown
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | accidental degeneracy | accidental double |
- Primary specie
- (CO3)2-
- Label (type)
- 3ν3 (stretching asym.) Bond: (CO3)2-
- Comments
- C-O asymmetric stretch
Vibration modes
- Label
- 2ν3+2ν4
- Category
- combination vibration
Evaluation
- Level
- fully assigned
- Evaluation
- undefined
- Comments
- attribution SSHADE
- Contribution level
- unknown
| # | Multiplicity type | Degeneracy | Other band |
|---|---|---|---|
| 1 | accidental degeneracy | accidental double |
- Primary specie
- (CO3)2-
- Temperature
- 295.0 ± 5.0 K
Temperature
- Pressure
- 1 bar
Pressure
- Method #1
- various
- Overlap
- moderately blended
- Peak
- 4275 ± 5 cm-1 (fit peak)
- Evaluation
- validated
- Quality
- C
- FWHM
- 68 ± 2 cm-1 (hwhm)
- Shape
- asymmetric
- Evaluation
- validated
- Quality
- D
- Method
- baseline corrected peak intensity
- Relative intensity
- 3.0e-04 ± 5.0e-05
- Strength
- weak (w)
- Evaluation
- undefined
- Quality
- D