Band
Title
3862.0 cm-1: ν34 of C2H2 in C2H2 - Metastable phase
Type
absorption
Assignments summary
Assignment Symmetry Mode Specie(s) Molecule/Atom Bond Multiplicity Degeneracy Contribution Resonance
ν34 combination vibration C2H2 C2H2 ≥ C-H
-C ≡ C-H
unknown
Characteristics summary
Peak position
(cm-1)
Center position
(cm-1)
Width
(cm-1)
Shape Asymmetry factor Peak intensity
(cm-1)
Peak intensity relative Peak strength Integrated intensity
(cm-2)
Integrated intensity relative Integrated strength Temperature
(K)
Pressure
(bar)
3862 ± 2 - 20 asymmetric 0.0035 m 50.0
Label
ν34
Category
combination vibration

Evaluation

Level
partly assigned
Evaluation
uncertain
Comments
Bottger & Eggers 1964
# Multiplicity type Degeneracy Other band
1 unknown

Vibration modes

Label (type)
ν3 (stretching asym.)       Bond: ≥ C-H
ν4 (bending asym.)       Bond: -C ≡ C-H
Texture
film

Temperature

Temperature
50.0 ± 5.0 K
Formation temperature
12.0 K
Temperature max
50.0 K
Method #1
spectrum measurement
Overlap
multiple
Peak
3862 ± 2 cm-1 (peak)
Evaluation
validated
Quality
B
Comments
possibly double band 3859, 3864 cm-1
FWHM
20 cm-1 (fwhm)
Shape
asymmetric
Evaluation
undefined
Quality
undefined
Method
baseline corrected peak intensity
Relative intensity
0.0035 ± 2.0e-04
Strength
medium (m)
Evaluation
undefined
Quality
C
Method
width x peak intensity
Evaluation
validated
Quality
undefined