Bandlist 71 71

Absorption band list of CH4 in natural solid CH4 (phase I)

Title
Absorption band list of CH4 in natural solid CH4 (phase I)
Type
absorption
Description
FIR-MIR-NIR-Vis absorption band list of the isotopes of CH4 in natural solid CH4 (phase I) at 30 and 90 K
Number of bands
71
Comments
The ν1 and ν2 modes are inactive in the IR. The ν3 mode is affected by free rotation of CH4 in phase I.
Position (cm-1) Width (cm-1) Peak intensity (cm-1) Relative intensity Strength Transition mode Mode type(s) Bond Specie(s) Degeneracy Resonances
160 ± 10 160 ± 10 130 ± 15 1 ± 0.1 1.25e-04 vw
νR
hindered rotation
12CH4
other
1299 ± 0.5 1299 ± 0.5 8000 ± 300 1 vs
ν4
deformation
12C-1H
12CH4
triple
2598 ± 2 2598 ± 2 24.8 ± 0.5 0.0031 m
4
deformation
12C-1H
12CH4

2819 ± 2 2819 ± 2 133 ± 2 0.016625 s
ν24
deformation
deformation
12C-1H
12C-1H
12CH4

3009 ± 2 3009 ± 2 5300 ± 200 0.6625 vs
ν3 + nνR
stretching asym.
hindered rotation
12C-1H
12CH4
other
3846 ± 1 3846 ± 1 48.4 ± 1 0.00605 m
4
deformation
12C-1H
12CH4

3897 ± 4 3897 ± 4 3.39 ± 0.05 4.237e-04 w
4
deformation
12C-1H
12CH4

4116 ± 1 4116 ± 1 9.59 ± 0.2 0.0012 w
ν2+2ν4
deformation
deformation
12C-1H
12C-1H
12CH4

4203 ± 1 4203 ± 1 515 ± 10 0.064375 s
ν14
stretching sym.
deformation
12C-1H
12C-1H
12CH4

4304 ± 1 4304 ± 1 267 ± 5 0.033375 s
ν34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

4530 ± 1 4530 ± 1 41.3 ± 1 0.00516 m
ν23
deformation
stretching asym.
12C-1H
12C-1H
12CH4

5114 ± 1 5114 ± 1 0.19 ± 0.004 2.375e-05 vw
4
deformation
12C-1H
12CH4

5162 ± 1 5162 ± 1 0.335 ± 0.007 4.188e-05 vw
4
deformation
12C-1H
12CH4

5384 ± 1 5384 ± 1 1.43 ± 0.03 1.788e-04 w
ν2+3ν4
deformation
deformation
12C-1H
12C-1H
12CH4

5507 ± 1 5507 ± 1 0.305 ± 0.02 3.812e-05 vw
?
unknown
12CH4

5566 ± 1 5566 ± 1 11.6 ± 0.2 0.00145 w
ν3+2ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

5596 ± 1 5596 ± 1 5.7 ± 0.1 7.125e-04 w
2+2ν4
deformation
deformation
12C-1H
12C-1H
12CH4


5800 ± 1 5800 ± 1 14.8 ± 0.3 0.00185 m
ν234
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

5848 ± 5 5848 ± 5 1.85 ± 0.15 2.313e-04 w
1
stretching sym.
12C-1H
12CH4

5919 ± 1 5919 ± 1 2.54 ± 0.04 3.175e-04 w
ν13
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

5990 ± 1 5990 ± 1 27 ± 0.5 0.00337 m
3
stretching asym.
12C-1H
12CH4

6034 ± 2 6034 ± 2 7.59 ± 0.15 9.488e-04 w
23
deformation
stretching asym.
12C-1H
12C-1H
12CH4

6616 ± 2 6616 ± 2 0.03 ± 5.0e-04 3.75e-06 vvw
ν2+4ν4
deformation
deformation
12C-1H
12C-1H
12CH4

6735 ± 1 6735 ± 1 0.649 ± 0.015 8.112e-05 vw
ν1+3ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

6858 ± 3 6858 ± 3 0.259 ± 0.005 3.238e-05 vw
ν3+3ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

6882 ± 3 6882 ± 3 0.286 ± 0.005 3.575e-05 vw
2+3ν4
deformation
deformation
12C-1H
12C-1H
12CH4

6999 ± 2 6999 ± 2 0.312 ± 0.005 3.9e-05 vw
ν12+2ν4
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

7066 ± 2 7066 ± 2 2.83 ± 0.05 3.538e-04 w
14
stretching sym.
deformation
12C-1H
12C-1H
12CH4

7084 ± 2 7084 ± 2 2.88 ± 0.05 3.6e-04 w
ν23+2ν4
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

7130 ± 2 7130 ± 2 3.71 ± 0.07 4.638e-04 w
ν134
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

7195 ± 3 7195 ± 3 1.15 ± 0.02 1.437e-04 w
ν1+2ν24
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

7233 ± 2 7233 ± 2 1.83 ± 0.04 2.288e-04 w
2+2ν4
deformation
deformation
12C-1H
12C-1H
12CH4

7279 ± 3 7279 ± 3 2.28 ± 0.05 2.85e-04 w
34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

7303 ± 3 7303 ± 3 2.61 ± 0.05 3.262e-04 w
234
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

7351 ± 3 7351 ± 3 2.77 ± 0.05 3.462e-04 w
ν123
stretching sym.
deformation
stretching asym.
12C-1H
12C-1H
12C-1H
12CH4

7488 ± 1 7488 ± 1 5.23 ± 0.1 6.538e-04 w
ν2+2ν3
deformation
stretching asym.
12C-1H
12C-1H
12CH4

8045 ± 1 8045 ± 1 0.0463 ± 0.001 5.788e-06 vvw
ν1+4ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

8087 ± 1 8087 ± 1 0.0494 ± 0.001 6.175e-06 vvw
ν3+4ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

8257 ± 2 8257 ± 2 0.0885 ± 0.002 1.106e-05 vvw
ν12+3ν4
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

8307 ± 1 8307 ± 1 0.36 ± 0.007 4.5e-05 vw
ν23+3ν4
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

8389 ± 1 8389 ± 1 0.887 ± 0.02 1.109e-04 vw
1+2ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

8409 ± 1 8409 ± 1 0.829 ± 0.02 1.036e-04 vw
ν13+2ν4
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

8542 ± 5 8542 ± 5 1.39 ± 0.03 1.737e-04 w
34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

8587 ± 1 8587 ± 1 4.77 ± 0.1 5.962e-04 w
124
stretching sym.
deformation
deformation
12C-1H
12C-1H
12C-1H
12CH4

8630 ± 3 8630 ± 3 0.8 ± 0.2 1.0e-04 vw
?
unknown
12CH4

8758 ± 2 8758 ± 2 1.09 ± 0.02 1.363e-04 vw
13
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

8782 ± 1 8782 ± 1 2.59 ± 0.05 3.237e-04 w
ν2+2ν34
deformation
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

8881 ± 1 8881 ± 1 0.955 ± 0.02 1.194e-04 vw
ν1+2ν3
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

9021 ± 2 9021 ± 2 0.109 ± 0.002 1.363e-05 vw
3
stretching asym.
12C-1H
12CH4

9688 ± 3 9688 ± 3 0.023 ± 0.001 2.875e-06 vvw
?
unknown
12CH4

9734 ± 1 9734 ± 1 0.0317 ± 6.0e-04 3.962e-06 vvw
ν13+3ν4
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

9855 ± 2 9855 ± 2 0.206 ± 0.004 2.575e-05 vw
3+3ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

9980 ± 1 9980 ± 1 0.143 ± 0.003 1.788e-05 w
14
stretching sym.
deformation
12C-1H
12C-1H
12CH4

10014 ± 4 10014 ± 4 0.0836 ± 0.0015 1.045e-05 vvw
134
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

10081 ± 2 10081 ± 2 0.252 ± 0.005 3.15e-05 vw
ν1+2ν34
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

10244 ± 4 10244 ± 4 0.05 ± 0.01 6.25e-06 vvw
?
unknown
12CH4

10270 ± 2 10270 ± 2 0.114 ± 0.002 1.425e-05 vvw
34
stretching asym.
deformation
12C-1H
12C-1H
12CH4

10466 ± 4 10466 ± 4 0.00305 ± 1.5e-04 3.813e-07 ew
ν2+3ν3
deformation
stretching asym.
12C-1H
12C-1H
12CH4

10514 ± 3 10514 ± 3 0.005 ± 2.5e-04 6.25e-07 ew
2+2ν3
deformation
stretching asym.
12C-1H
12C-1H
12CH4

10888 ± 6 10888 ± 6 0.0077 ± 5.0e-04 9.625e-07 ew
3+2ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

11088 ± 1 11088 ± 1 0.182 ± 0.004 2.275e-05 vw
3+4ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

11151 ± 2 11151 ± 2 0.167 ± 0.004 2.087e-05 vw
1+2ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

11240 ± 1 11240 ± 1 0.549 ± 0.01 6.863e-05 vw
13+2ν4
stretching sym.
stretching asym.
deformation
12C-1H
12C-1H
12C-1H
12CH4

11506 ± 2 11506 ± 2 0.0748 ± 0.0015 9.35e-06 vvw
3+2ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

11584 ± 2 11584 ± 2 0.036 ± 0.001 4.5e-06 vvw
?
unknown
12CH4

11846 ± 3 11846 ± 3 0.0111 ± 3.0e-04 1.388e-06 ew
ν1+3ν3
stretching sym.
stretching asym.
12C-1H
12C-1H
12CH4

11884 ± 3 11884 ± 3 0.011 ± 3.0e-04 1.375e-06 ew
3
stretching asym.
12C-1H
12CH4

12511 ± 4 12511 ± 4 0.0145 ± 3.0e-04 1.813e-06 vvw
1+3ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

12719 ± 3 12719 ± 3 0.0135 ± 2.5e-04 1.687e-06 vvw
3+3ν4
stretching asym.
deformation
12C-1H
12C-1H
12CH4

13706 ± 3 13706 ± 3 0.0525 ± 0.001 6.563e-06 vvw
1+4ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

13835 ± 4 13835 ± 4 0.022 ± 0.001 2.75e-06 vvw
1+4ν4
stretching sym.
deformation
12C-1H
12C-1H
12CH4

Spectral range type(s)
NIR, MIR, FIR
Spectral range(s)
100 - 13900 cm-1
Reference position infrared
1300 cm-1

Versions

Release date
2022-02-23 15:28:48 UTC+0000
Version (Date)
#2 (2022-02-23 15:28:48 UTC+0000)
Older version(s)
History
Date Mode Version Status Comments
2021-10-01 08:14:49 UTC+0000 first import #1
Analysis
currently limited to the data and compilation in Khanna and Ngoh (1990), Quirico et al. (1997a) and Grundy et al. (2002) papers
Quality flag
4
Validation date
2021-08-11
Validators