Solid phase
Official name
Selenium
CAS number
7782-49-2
Family
metallic solid
Class
pseudometal (semi-conductor)
Compound type
elemental solid
Comments
There are also $/alpha-, /beta- & /gamma-$ Se phases d containing Se8 rings (monoclinic/prismatic, 2/m (C2h), P2(1)/c)
Formula
$Se$
Chemical formula
Se
Elemental formula
Se
Isotope mixture type
terrestrial abundance
2.0
  Formula Name Family Number min-max Mole fraction Isotope mole fraction State Relevance
$Se$ Selenium element 1 1.0 1 constituent element main
Composition comments
helical polymeric chains of Se
Chemical bonds
  Bond Number
$-Se-Se-$ 8
Class
pseudometals (14)
Type
homovalent monolayer pseudometals (14.01)
Phase name
gray selenium
Phase type
crystalline
Crystal system
trigonal
Crystal class
trapezohedral
Crystal class symbol
32 (D3)
Crystal spacegroup
P3(1)21
Comments
Chiral hexagonal crystal lattice, that can also have the crystal_spacegroup P3(2)21 (group 154) depending on the chirality.
Molar mass
78.971 $g/mol$
Density
4.81 $g/cm^3$
State NTP
solid
Phase transitions
Phase transition type Other phases Temperature - Pressure
solid-solid from other allotropes > 180°C (> 453 K)
solid-liquid liquid Se 494 K ​(221 °C)
Phase transitions comments
Gray Se is formed by mild heating of other allotropes, by slow cooling of molten Se, or by condensing Se vapor just below the melting point.
Refringence type
uniaxial
Refringence sign
positive
Birefringence
1.04
Refraction index $n_{\alpha}$
3.00
Refraction index $n_{\beta}$
4.04
Pure color
gray
Color
gray, purple gray, reddish
Diaphaneity
opaque
Luster
submetallic