Solid phase
Official name
Magnesium(II) sulfate hexahydrate
Secondary names
Magnesium sulphate hexahydrate
CAS number
13778-97-7
Family
ionic solid
Class
normal salt
Compound type
sulfate
Comments
Magnesium sulfate hexahydrate occurs as a mineral: Hexahydrite
Formula
Mg2+SO246H2O
Chemical formula
MgSO4•6H2O
Elemental formula
(Mg2+) S O8 (O-)2 H12
Isotope mixture type
terrestrial abundance
16.0
  Formula Name Family Number min-max Mole fraction Isotope mole fraction State Relevance
Mg2+ Magnesium(II) cation element 1 0.125 1 constituent cation main
(SO4)2 Sulfate anion chemical function 1 0.125 1 anionic radical main
H2O Water molecule 6 0.75 1 hydration main
Chemical functions
  Function Number
(SO4)2 1
ROH 2
Chemical bonds
  Bond Number
Mg2+O 2
OH 12
OH 2
4
Class
normal salts (07)
Type
hydrated simple normal salts (07.04)
Equivalent mineral
Hexahydrite
Phase type
crystalline
Crystal system
monoclinic
Crystal class
prismatic
Crystal class symbol
2/m (C2h)
Crystal spacegroup
C2/c
Molar mass
228.46 g/mol
Density
1.76 g/cm^3
State NTP
solid
Phase transitions
Phase transition type Other phases Temperature - Pressure
solid-solid MgSO4.H2O + H2O(liq) above 68°C (341 K)
solid-solid MgSO4.H2O below 42% RH
solid-solid MgSO4.7H2O below 48°C (321 K)
solid-solid MgSO4.7H2O above 51% RH
Phase transitions comments
hydrates to Epsomite in humid air
Refringence type
biaxial
Refringence sign
negative
Birefringence
0.028
Refraction index n_{\alpha}
1.426
Refraction index n_{\beta}
1.453
Refraction index n_{\gamma}
1.456
Dispersion V
none
Pure color
colorless
Color
colorless, white
Diaphaneity
transparent to translucent
Luster
vitreous