Publication
Names
  • L. Zhou
  • R. I. Kaiser
  • A. T. Tokunaga
Title
Infrared spectroscopy of crystalline and amorphous diacetylene (C $_4$H $_2$) and implications for Titan's atmospheric composition
Abstract
New laboratory spectra of crystalline and amorphous diacetylene ice have been recorded in the range of 7000-500 cm$^-1$ (1.4-20 μm) to aid in the identification of solid diacetylene on Saturn&'s moon Titan. We have established that amorphous diacetylene ice is stable only at temperatures less than 70$\pm$1 K. With respect to observations on Titan, the best approach would be to utilize future space-based telescopes to search for the ν$_4$ (3277/3271 cm$^-1$) in absorption against the reflected light from the sun and the slightly weaker ν$_8$ absorption bands (676/661 cm$^-1$) in absorption against the continuum emission.
Keywords
spectroscopy, transmission spectra, absorbance spectra, band position, band vibration mode, mid-IR, temperature, phase change, amorphous, crystal, molecular solid, C4H2
Content
spectral data, band list data, experimental physics
Year
2009
Journal
Planetary and Space Science
Volume
57
Number
7
Pages
830 - 835
Pages number
6
Document type
article
Publication state
published