- Names
-
- Qiushi Guan
- Yuan Mei
- Barbara Etschmann
- Denis Testemale
- Marion Louvel
- Joël Brugger
- Title
- Yttrium complexation and hydration in chloride-rich hydrothermal fluids: A combined ab initio molecular dynamics and in situ X-ray absorption spectroscopy study
- Abstract
- Accurate knowledge of rare earth elements (REE) speciation in high pressure – high temperature fluids is required to model REE transport and precipitation in subduction zones and magmatic-hydrothermal environments, and the formation of rare metal deposits. Recent experiments (lanthanum, ytterbium, erbium) have demonstrated that REE chloride complexes are the main REE form in many hydrothermal fluids (Migdisov et al., 2016). However, the speciation of yttrium (Y(III)), a cation with an ionic radius similar to that of Ho(III), remains poorly constrained in chloride-rich hydrothermal solutions.
- Keywords
- yttrium chloride complexes, hydrothermal, x-ray absorption spectroscopy
- Content
- earth sciences
- Year
- 2020
- Journal
- Geochimica et Cosmochimica Acta
- Volume
- 281
- Pages
- 168
- Document type
- article
- Publication state
- published
- Doi
- 10.1016/j.gca.2020.04.015
- Identifiers
-
- bibcode: guan_yttrium_2020
- Experiment/Spectra
-
- Y K edge XAS transmission of synthetic yttrium oxide Y2O3 at ambient conditions
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 10.02m Li 9.49m HCl 0.5m, 800 bar 30°C) at 800 bar and 30°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 10.02m Li 9.49m HCl 0.5m, 800 bar 30°C) at 800 bar and 200°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 10.02m Li 9.49m HCl 0.5m, 800 bar 30°C) at 800 bar and 300°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 10.02m Li 9.49m HCl 0.5m, 800 bar 30°C) at 800 bar and 350°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 10.02m Li 9.49m HCl 0.5m, 800 bar 30°C) at 800 bar and 400°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 10.02m Li 9.49m HCl 0.5m, 800 bar 30°C) at 800 bar and 450°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.01m Cl 0.03m HCl 0.002m) at 800 bar and 30°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.01m Cl 0.03m HCl 0.002m) at 800 bar and 200°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.01m Cl 0.03m HCl 0.002m) at 800 bar and 300°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.01m Cl 0.03m HCl 0.002m) at 800 bar and 350°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.01m Cl 0.03m HCl 0.002m) at 800 bar and 400°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 0.79m HCl 0.75m) at 800 bar and 30°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 0.79m HCl 0.75m) at 800 bar and 200°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 0.79m HCl 0.75m) at 800 bar and 300°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 0.79m HCl 0.75m) at 800 bar and 350°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.011m Cl 0.79m HCl 0.75m) at 800 bar and 450°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.012m Cl 2.52m Na 1.99m HCl 0.5m) at 800 bar and 30°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.012m Cl 2.52m Na 1.99m HCl 0.5m) at 800 bar and 200°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.012m Cl 2.52m Na 1.99m HCl 0.5m) at 800 bar and 300°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.012m Cl 2.52m Na 1.99m HCl 0.5m) at 800 bar and 350°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.92m Cl 2.76m) at 800 bar and 30°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.92m Cl 2.76m) at 800 bar and 200°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.92m Cl 2.76m) at 800 bar and 300°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.92m Cl 2.76m) at 800 bar and 350°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.92m Cl 2.76m) at 800 bar and 400°C
- Y K edge XAS fluorescence of yttrium(III) solution at hydrothermal conditions (Y 0.92m Cl 2.76m) at 800 bar and 450°C