Publication
Names
  • Romain Cerubini
  • Antoine Pommerol
  • André Galli
  • Bernhard Jost
  • Peter Wurz
  • Nicolas Thomas
Title
VIS spectroscopy of NaCl - water ice mixtures irradiated with 1 and 5 keV electrons under Europa's conditions: Formation of colour centres and Na colloids
Abstract
Recent laboratory efforts and telescopic observations of Europa have shown the relevance of a yellow colouration of sodium chloride (NaCl) caused by crystal defects generated by irradiation. We further investigate this process by irradiating (with energetic electrons) different types of analogues where NaCl is associated in different ways to water ice. We produce two types of icy analogues: compact slabs and granular particles where we investigate two particle sizes (5 and 70 μm). We perform electron irradiation at cryogenic temperatures (100K) and under high vacuum (10-7 mbar) conditions, with energies of 1 and 5 keV. We observe the formation of two different types of colour centres. The so-called F-centres (460 nm) were formed in every sample, but the intensity of the absorption band within the compact slabs surpassed any other icy analogues and was comparable to the intensity of the absorption band within pure NaCl grains. M-centres (720 nm) have not been detected at the surface of Europa so far, and were close to the detection limit during our irradiation of compact slabs. The slabs could be good analogues for Europa's surface as they produce mainly F-centres. Other notable differences have been observed between compact slabs and granular samples, such as the presence of an absorption band at 580 nm attributed to colloids of Na, exclusively within granular samples. Such absorptions have not been reported in previous studies.
Keywords
Reflectance, H2O ice, Salts, Icy Moons
Content
spectral data, sample, material-matter
Year
2022
Journal
Icarus
Volume
379
Pages
114977
Document type
article
Publication state
published