Publication
Names
  • Julien Bonnet
  • Jean Cauzid
  • Denis Testemale
  • Isabelle Kieffer
  • Olivier Proux
  • Andreï Lecomte
  • Laurent Bailly
Title
Characterization of Germanium Speciation in Sphalerite (ZnS) from Central and Eastern Tennessee, USA, by X-ray Absorption Spectroscopy
Abstract
X-ray absorption near edge structure (XANES) spectroscopy was used on zoned sphalerites (ZnS) from two world-class Mississippi Valley Type deposits, the Central and Eastern Tennessee Mining district, USA, in order to investigate germanium oxidation states. Due to the low germanium concentrations of these samples, it was necessary to perform the X-ray absorption spectroscopy (XAS) in fluorescence mode. The overlapping of the Zn Kβ and Ge Kα emission lines meant that a high energy-resolution was required. This was achieved using crystal analysers and allowed a bandwidth of 1.3 eV to be obtained. Experimental spectra were compared to XANES calculations and three configurations of germanium incorporation into sphalerite were identified. The first two, the most prevalent, show germanium (II) and (IV) surrounded by sulphur atoms in tetrahedral coordination, suggesting the replacement of Zn by Ge. In the third configuration, germanium (IV) is surrounded by oxygen atoms. This third configuration is unexpected for a zinc sulphide mineral and it resembles that of argutite (GeO2).
Keywords
XANES spectroscopy, sphalerite, germanium, oxidation state
Content
spectral data, earth sciences
Year
2017
Journal
Minerals
Volume
7
Number
5
Pages
79
Pages number
16
Document type
article
Publication state
published