Publication
Names
  • M. Battandier
  • L. Bonal
  • E. Quirico
  • P. Beck
  • C. Engrand
  • J. Duprat
  • E. Dartois
Title
Characterization of the organic matter and hydration state of Antarctic Micrometeorites: a reservoir distinct from carbonaceous chondrites
Abstract
This work presents a multi-analysis on 36 Antarctic micrometeorites (AMMs) (Concordia collection 2006) by coupled Raman and Infrared (IR) spectroscopies, in comparison with samples from type 1 and 2 carbonaceous CM, CR and CI chondrites. We identified the Raman G- and D-bands revealing the presence of polyaromatic carbonaceous material on raw particles in a subset of 18 particles. Thirteen AMMs (11 Fg + 1 Fg-Sc + 1 Sc) were selected from this first subset, and analyzed by infrared microscopy along with 4 AMMs (3 Fg + 1 Fg-Sc + 1Sc) from a previous study by Dobrica et al. (2009). These analyses showed that scoriaceous, fine-grained scoriaceous and part of the fine-grained AMMs are not hydrated, with a weak abundance of carbonaceous matter. According to the Raman criterion defined by Dobrica et al. (2009), hydrous AMMs do not show structural modifications induced by heating through the atmospheric entry. In several hydrous AMMs, the carbonaceous matter abundance is found larger than in Orgueil (CI), Murchison (CM) and QUE 99177 (CR) chondrites and their mineral content exhibit differences reflected by the structure of the silicate 10 µm band. These observations suggest that part of the AMMs originates from one, or several, distinct parent bodies with respect to primitive carbonaceous chondrites. Each hydrous Fg-AMMS displays higher CH2/CH3 ratio and a smaller carbonyl abundance than chondrites, which point toward a mild processing during atmospheric entry, possibly oxidation, which did not modify the carbon backbone and therefore do not induce differences in Raman spectroscopy.
Keywords
micrometeorites, infrared, Raman, organic matter, spectroscopy
Content
spectral data, material-matter
Year
2018
Journal
Icarus
Volume
306
Pages
74 - 93
Pages number
20
Document type
article
Publication state
published
Comments
under minor revision in October 2017