Hydrogen sulfide-d2 | SSHADE

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Molecule

Name: Hydrogen sulfide-d2

Name and identifiers

IUPAC name: (32S,2H2)Hydrogen sulfide
Secondary names: Dihydrogen monosulfide, Dihydrogen sulfide, Hydrosulfuric acid, Hydrogen sulphide, Hydrogen monosulfide, D2S
InChI: InChI=1S/H2S/h1H2/i1+0/hD2
InChI key: RWSOTUBLDIXVET-GGAQIHGBSA-N
Comments: $D_2^{32}S$ isotope

Structure and atomic composition

Formula: $D_2~^{32}S$
Chemical formula: H2S
Isotopic formula: D2[32]S
Structural formula: [2H][32S][2H]
Charge: 0
Unpaired electrons: 0

	Atom	Name	Number
	$^2H$ or $D$	Hydrogen	2
	$^{32}S$	Sulfur	1

Relations

no

Isotopic composition

Isotope mixture type: pure isotope

Nuclear spin isomers

Spin type: unique

Molar mass: 36.000275 $g/mol$
State STP: gas
Protic: protic
Polarity: polar
Dipole: 0.97833 $D$

Fundamental vibration modes

Molecule symmetry

C2v

Case

nonlinear-triatomic

Vibrations number

3

Vibrations

Label	Mode	Bond	Symmetry	Degeneracy	Fundamental frequency	Observed frequency	Observed frequency	Harmonic frequency	Activity IR	Activity Raman	Strength	Comments
V1	stretching sym.	$D_2~^{32}S$	$A_{1}$	no	1896.0	1896.38			active	active	m	Raman: 1981.6 $cm^{-1}$ (gas)
V2	bending	$D_2~^{32}S$	$A_{1}$	no	855.0	855.45			active	active	s
V3	stretching asym.	$D_2~^{32}S$	$B_{1}$	no	1999.0	1999.0			active	active	m

Comments

Data from NIST Chemistry WebBook

Publications

Shimanouchi, 1972, Natl. Bur. Stand., 39, 1 - 160

Chemical functions and bonds

Chemical bonds

	Bond	Number
	$-^{32}S-D$	2