Constituent
Name
Orpiment
IMA name
Orpiment
Class
non-silicate mineral
Compound type
sulfide
Comments
Common impurities: Hg, Ge, Sb
Relevance
main - minor
Arrangement
in multi-phases
Formula
$As_2S_3$
Chemical formula
As2S3
Elemental formula
As2 S3
Isotope mixture type
terrestrial abundance
  Formula Name Family Number min-max Isotope mole fraction State Relevance
$As$ Arsenic element 2 constituent element main
$S$ Sulfur element 3 constituent element main
Composition comments
Polymeric solid
Chemical bonds
  Bond Number
$As-S$ 6
Oxides comments
As: 60.9%, S: 39.1%

Strunz

Class
sulfides - sufosalts (02)
Division
sulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2O (02.F)
Family
With As, (Sb), S (02.FA)
Code
02.FA.30

Dana

Major class
sulfides (II)
Class
sulfides - including selenides and tellurides (02)
Type
where Am Bn Xp, with (m+n):p=2:3 (02.11)
Group
Orpiment group (02.11.01)
Code
02.11.01.01
Phase type
crystalline
Crystal system
monoclinic
Crystal class
prismatic
Crystal class symbol
2/m (C2h)
Crystal spacegroup
P2(1)/m
Molar mass
246.04 $g/mol$
Density
3.49 - 3.56 $g/cm^3$
Refringence type
biaxial
Refringence sign
negative
Birefringence
0.620
Refraction index $n_{\alpha}$
2.40
Refraction index $n_{\beta}$
2.81
Refraction index $n_{\gamma}$
3.02
Dispersion V
r > v strong
Color
lemon yellow, brownish yellow, orange yellow
Diaphaneity
transparent to translucent
Luster
pearly