Constituent
Name
K-exchanged saponite SAP size-fraction <2 µm
IMA name
Saponite
Class
silicate mineral
Compound type
phyllosilicate
Comments
Chemical composition and molecular mass are per half unit cell
Relevance
main - major
Arrangement
homogeneous in multi-phases
Mass fraction
1.0 $\pm$ 0.05
Formula
$K_{0.58}(Mg_{3})(Si_{3.42}Al_{0.58})O_{10}(OH)_2$
Chemical formula
(Na,Ca0.5)0.3(Mg,Fe2+)3(Si,Al)4O10(OH)2•4(H2O)
Elemental formula
K0.58 (Al)0.58-1.5 Mg3 (Si)3.42-4 (O)12-16 (H)2-10
Isotope mixture type
terrestrial abundance
  Formula Name Family Number min-max Isotope mole fraction State Relevance
$K$ Potassium element 0.58 1.0 constituent element main
$Al$ Aluminium element 0.58 - 1.5 1.0 constituent element main
$Mg$ Magnesium element 3 1.0 constituent element main
$Si$ Silicon element 3.42 - 4 1.0 constituent element main
$O$ Oxygen element 12 - 16 1.0 constituent element main
$H$ Hydrogen element 2 - 10 1.0 constituent element main
Composition comments
Typical formula: $(Ca_{0.1}Na_{0.1})(Mg_{2.25}Fe^{2+}_{0.75}).(Si_3Al)O_{10}(OH)_2 \bullet 4(H_2O)$ - Common impurities: Ti, Mn, Ni, K, P - Intermolecular water was not taken into account in atomic composition calculation
Chemical functions
  Function Number
$(OH)^-$ 2
Chemical bonds
  Bond Number
$O^--H$ 1
Oxides
Formula $SiO_{2}$ $Al_{2}O_{3}$ $MgO$ $H_{2}O$ $K_{2}O$
Mass fraction (%) 51.2 7.37 30.14 4.49 7.96

Strunz

Class
silicates (09)
Division
phyllosilicate (09.E)
Family
Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets (09.EC)
Code
09.EC.45

Dana

Major class
silicates (VIII)
Class
phyllosilicate sheets of six-membered rings (71)
Type
with 2:1 clays (71.03)
Group
Smectite group (Trioctahedral Smectites) (71.03.01b)
Code
71.03.01b.02
Phase type
crystalline
Crystal system
monoclinic
Crystal class
prismatic
Crystal class symbol
2/m (C2h)
Crystal spacegroup
C2/m
Texture
cryptocrystalline
Molar mass
401.0 $g/mol$
Density
N/A $g/cm^3$
Refringence type
biaxial
Refringence sign
negative
Birefringence
0.032 - 0.037
Refraction index $n_{\alpha}$
1.479 - 1.49
Refraction index $n_{\beta}$
1.51 - 1.525
Refraction index $n_{\gamma}$
1.511 - 1.527
Color
white, yellowish white, greenish white, reddish white, bluish white
Diaphaneity
subtranslucent to opaque
Luster
N/A